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Sunil Galani, Kirti kumar Goswami, Bhagwati K. Gauni Mehariya, Krunalkumar R. Mehariya, Ranjit S. Pada, Dipak Vachhani (Beteiligte)

X-Ray Crystallographic Study of Novel Oxazole Derivatives


Mitarbeit: Mehariya, Krunalkumar R.; Mehariya, Bhagwati K. Gauni; Goswami, Kirti kumar; Vachhani, Dipak; Galani, Sunil; Pada, Ranjit S.
2016. 40 S. 220 mm
Verlag/Jahr: ANCHOR ACADEMIC PUBLISHING 2016
ISBN: 3-9606708-3-4 (3960670834)
Neue ISBN: 978-3-9606708-3-4 (9783960670834)

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This book is the outcome of an examination of single organic molecules through single-crystal X-ray techniques. The book is suitable for research scholars as it covers a complete analysis of novel oxazole derivatives by single-crystal X-ray techniques.
Text sample:
Chapter 4.1.1: Data Collection:
A colorless prism crystal of C13H11NO3 having approximate dimensions of 0.560 ˛ 0.480 ˛ 0.300 mm was mounted on a glass fiber.
All measurements were made on a Rigaku SCX mini diffractometer using graphite monochromated Mo-K radiation.
The crystal-to-detector distance was 52.00 mm. Cell constants and an orientation matrix for data collection corresponded to a primitive orthorhombic cell with dimensions: a = 17.421(4) ¸, b = 18.581(4) ¸, c = 6.882(2) ¸, V = 2227.6(8) ¸3.
For Z = 8 and F.W. = 229.23, the calculated density is 1.367 g/cm3. Based on the reflection conditions of:0kl: k+l = 2n and h0l: h = 2n.
Packing considerations, a statistical analysis of intensity distribution, and the successful solution and refinement of the structure, the space group was determined to be:Pna21 (33).
The data were collected at a temperature of 20 + 1 °C to a maximum 2th value of 55.0°.
A total of 540 oscillation images were collected. A sweep of data was done using oscillations from -120.0 to 60.0° in 1.0° steps.
The exposure rate was 10.0 [sec./°]. The detector swing angle was -30.80°.
A second sweep was performed using oscillations from -120.0 to 60.0° in 1.0° steps.
The exposure rate was 10.0 [sec./°].
The detector swing angle was -30.80°.
Another sweep was performed using oscillations from -120.0 to 60.0° in 1.0° steps.
The detector swing angle was -30.80°.
The crystal-to-detector distance was 52.00 mm.
Readout was performed in the 0.146 mm pixel mode.
The author is a science student and currently working as an assistant professor at the Gujarat Arts & Science College, Ahmedabad.